Literature DB >> 15704924

Copper-mediated cross-coupling of H-phosphonates with vinyliodonium salts: a novel very mild synthesis of 2-arylvinylphosphonates.

Sabine Thielges1, Philippe Bisseret, Jacques Eustache.   

Abstract

We report a novel, very mild, highly stereoselective preparation of 2-arylvinylphosphonates at room temperature that involves the copper iodide-mediated cross-coupling of H-phosphonates with vinyliodonium tetrafluoroborates. [Structure: see text]

Entities:  

Year:  2005        PMID： 15704924     DOI： 10.1021/ol047516y

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

Review 1.  Chemistry of polyvalent iodine.

Authors:  Viktor V Zhdankin; Peter J Stang
Journal:  Chem Rev       Date:  2008-12       Impact factor: 60.622

2.  Enantioselective α-vinylation of aldehydes via the synergistic combination of copper and amine catalysis.

Authors:  Eduardas Skucas; David W C MacMillan
Journal:  J Am Chem Soc       Date:  2012-05-29       Impact factor: 15.419

3.  Enantioselective α-alkenylation of aldehydes with boronic acids via the synergistic combination of copper(II) and amine catalysis.

Authors:  Jason M Stevens; David W C MacMillan
Journal:  J Am Chem Soc       Date:  2013-08-05       Impact factor: 15.419

4.  Explaining Regiodivergent Vinylations with Vinylbenziodoxolones.

Authors:  Ester M Di Tommaso; Per-Ola Norrby; Berit Olofsson
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-08       Impact factor: 16.823

5.  Copper-catalyzed O-alkenylation of phosphonates.

Authors:  Nuria Vázquez-Galiñanes; Mariña Andón-Rodríguez; Patricia Gómez-Roibás; Martín Fañanás-Mastral
Journal:  Beilstein J Org Chem       Date:  2020-04-03       Impact factor: 2.883
  5 in total

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