Literature DB >> 15704893

Intramolecular Diels-Alder cycloadditions of fulvenes. Application to the kigelinol, neoamphilectane, and kempane skeletons.

Bor-Cherng Hong1, Fon-Len Chen, Shang-Hung Chen, Ju-Hsiou Liao, Gene-Hsiang Lee.   

Abstract

A variety of polycyclic ring skeletons (e.g., kigelinol, neoamphilectane, and kempene systems) can be prepared rapidly via intramolecular Diels-Alder cycloadditions (IMDA) of fulvenes. The length of the tethers and the diversity of the substituents on the fulvene core dictate the nature of the IMDA pathway. [reaction: see text]

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Year:  2005        PMID: 15704893     DOI: 10.1021/ol047730m

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  5 in total

1.  Chemistry of the Secondary Metabolites of Termites.

Authors:  Edda Gössinger
Journal:  Prog Chem Org Nat Prod       Date:  2019

2.  Two rare-class tricyclic diterpenes with antitubercular activity from the Caribbean sponge Svenzea flava. Application of vibrational circular dichroism spectroscopy for determining absolute configuration.

Authors:  Edward Avilés; Abimael D Rodríguez; Jan Vicente
Journal:  J Org Chem       Date:  2013-11-05       Impact factor: 4.354

3.  (3-Chloro-phen-yl){2-eth-oxy-5-[(Z)-hydroxy(phen-yl)methyl-idene]cyclo-penta-1,3-dien-1-yl}methanone.

Authors:  Mihaela-Liliana Tinţaş; Richard A Varga; Ion Grosu; Elena Bogdan
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-01-11

Review 4.  An overview of the cycloaddition chemistry of fulvenes and emerging applications.

Authors:  Ellen Swan; Kirsten Platts; Anton Blencowe
Journal:  Beilstein J Org Chem       Date:  2019-09-06       Impact factor: 2.883

5.  Tandem processes promoted by a hydrogen shift in 6-arylfulvenes bearing acetalic units at ortho position: a combined experimental and computational study.

Authors:  Mateo Alajarin; Marta Marin-Luna; Pilar Sanchez-Andrada; Angel Vidal
Journal:  Beilstein J Org Chem       Date:  2016-02-11       Impact factor: 2.883

  5 in total

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