Literature DB >> 15688146

Hairpin rubber elasticity.

J M Adams1, M Warner.   

Abstract

We model the elastic properties of main chain liquid crystalline elastomers, formed by cross linking chains in a strongly nematic state, when they have hairpin defects. We study the response of the elastomer to imposed uniaxial extension along the nematic direction, and employ a microscopic model of how the deformation is distributed non-affinely amongst the hairpin and straight chain populations. The rubber shows a plateau in the stress as a function of the elongation imposed along the director. It is a consequence of the depletion of the actively stretching population of hairpin chains and should not be confused with soft elasticity effects associated with director rotation.

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Year:  2005        PMID: 15688146     DOI: 10.1140/epje/e2005-00012-3

Source DB:  PubMed          Journal:  Eur Phys J E Soft Matter        ISSN: 1292-8941            Impact factor:   1.890


  6 in total

1.  Force-extension curve of a polymer in a high-frequency electric field.

Authors:  Adam E Cohen
Journal:  Phys Rev Lett       Date:  2003-12-04       Impact factor: 9.161

2.  Observation of hairpin defects in a nematic main-chain polyester.

Authors: 
Journal:  Phys Rev Lett       Date:  1993-04-12       Impact factor: 9.161

3.  Experimental evidence of chain extension at the transition temperature of a nematic polymer.

Authors: 
Journal:  Phys Rev Lett       Date:  1988-11-28       Impact factor: 9.161

4.  Giant dielectric response and hairpins in polymeric nematics.

Authors: 
Journal:  Phys Rev Lett       Date:  1987-01-26       Impact factor: 9.161

5.  Molecular individualism.

Authors:  P G de Gennes
Journal:  Science       Date:  1997-06-27       Impact factor: 47.728

6.  Effect of crosslinker geometry on equilibrium thermal and mechanical properties of nematic elastomers.

Authors:  S M Clarke; A Hotta; A R Tajbakhsh; E M Terentjev
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2001-11-08
  6 in total
  1 in total

1.  Internal constraints and arrested relaxation in main-chain nematic elastomers.

Authors:  Takuya Ohzono; Kaoru Katoh; Hiroyuki Minamikawa; Mohand O Saed; Eugene M Terentjev
Journal:  Nat Commun       Date:  2021-02-04       Impact factor: 14.919

  1 in total

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