| Literature DB >> 15688146 |
Abstract
We model the elastic properties of main chain liquid crystalline elastomers, formed by cross linking chains in a strongly nematic state, when they have hairpin defects. We study the response of the elastomer to imposed uniaxial extension along the nematic direction, and employ a microscopic model of how the deformation is distributed non-affinely amongst the hairpin and straight chain populations. The rubber shows a plateau in the stress as a function of the elongation imposed along the director. It is a consequence of the depletion of the actively stretching population of hairpin chains and should not be confused with soft elasticity effects associated with director rotation.Mesh:
Substances:
Year: 2005 PMID: 15688146 DOI: 10.1140/epje/e2005-00012-3
Source DB: PubMed Journal: Eur Phys J E Soft Matter ISSN: 1292-8941 Impact factor: 1.890