Literature DB >> 15685337

Molecular N2 complexes of iron stabilised by N-heterocyclic 'pincer' dicarbene ligands.

Andreas A Danopoulos1, Joseph A Wright, William B Motherwell.   

Abstract

The first N2 complex stabilised by N-heterocyclic carbene ligands, Fe(C-N-C)(N2)2, has been obtained by the reduction of Fe(C-N-C)Br2 where C-N-C = 2,6-bis(aryl-imidazol-2-ylidene)pyridine, aryl = 2,6-Pr(i)2C6H3, with Na(Hg); it serves as a convenient precursor for other iron NHC 'pincer' complexes of the type Fe(C-N-C)(N2)L where L = C2H4, PMe3 and Fe(C-N-C)(CO)2.

Entities:  

Year:  2004        PMID： 15685337     DOI： 10.1039/b415562a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  17 in total

1.  Low-temperature N2 binding to two-coordinate L2Fe(0) enables reductive trapping of L2FeN2(-) and NH3 generation.

Authors:  Gaël Ung; Jonas C Peters
Journal:  Angew Chem Int Ed Engl       Date:  2014-11-13       Impact factor: 15.336

2.  Oxidative Addition of Dihydrogen, Boron Compounds, and Aryl Halides to a Cobalt(I) Cation Supported by a Strong-Field Pincer Ligand.

Authors:  Stephan M Rummelt; Hongyu Zhong; Nadia G Léonard; Scott P Semproni; Paul J Chirik
Journal:  Organometallics       Date:  2019-02-20       Impact factor: 3.876

3.  Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications.

Authors:  Rebeca Arevalo; Paul J Chirik
Journal:  J Am Chem Soc       Date:  2019-05-28       Impact factor: 15.419

4.  The substitution reaction of (CNC)Fe-2N₂ with CO.

Authors:  Hongyan Liu; Shuangshuang Liu; Xiang Zhang
Journal:  J Mol Model       Date:  2013-03-17       Impact factor: 1.810

5.  Synthesis, Structure, and Hydrogenolysis of Pyridine Dicarbene Iron Dialkyl Complexes.

Authors:  Stephan M Rummelt; Jonathan M Darmon; Renyuan Pony Yu; Peter Viereck; Tyler P Pabst; Zoë R Turner; Grant W Margulieux; Shunlin Gu; Paul J Chirik
Journal:  Organometallics       Date:  2019-08-09       Impact factor: 3.876

6.  Nitrogenase-Relevant Reactivity of a Synthetic Iron-Sulfur-Carbon Site.

Authors:  Amy L Speelman; Ilija Čorić; Casey Van Stappen; Serena DeBeer; Brandon Q Mercado; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2019-08-12       Impact factor: 15.419

Review 7.  Insight into the Iron-Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands.

Authors:  Ilija Čorić; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2016-06-03       Impact factor: 15.419

8.  High-Activity Iron Catalysts for the Hydrogenation of Hindered, Unfunctionalized Alkenes.

Authors:  Renyuan Pony Yu; Jonathan M Darmon; Jordan M Hoyt; Grant W Margulieux; Zoë R Turner; Paul J Chirik
Journal:  ACS Catal       Date:  2012       Impact factor: 13.084

9.  Catalytic hydrogenation activity and electronic structure determination of bis(arylimidazol-2-ylidene)pyridine cobalt alkyl and hydride complexes.

Authors:  Renyuan Pony Yu; Jonathan M Darmon; Carsten Milsmann; Grant W Margulieux; S Chantal E Stieber; Serena DeBeer; Paul J Chirik
Journal:  J Am Chem Soc       Date:  2013-08-22       Impact factor: 15.419

10.  Iron-catalysed tritiation of pharmaceuticals.

Authors:  Renyuan Pony Yu; David Hesk; Nelo Rivera; István Pelczer; Paul J Chirik
Journal:  Nature       Date:  2016-01-14       Impact factor: 49.962
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