Literature DB >> 15685318

Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [Ge(II)N2]4- ions.

Zoltán A Gál1, Simon J Clarke.   

Abstract

The layered nitride Sr11Ge4N6 contains Ge4- Zintl anions in both [Sr4Ge]4+ layers and [GeN2Sr7]4+ antiperovskite-type slabs which are separated by sheets of bent [Ge(II)N2]4- ions; the observed range of formal germanium oxidation states in nitrides thus extends between +4 and -4.

Entities:  

Year:  2004        PMID： 15685318     DOI： 10.1039/b413534b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

1.  The Reduced Nitridogermanates(III) Ca6 [Ge2 N6 ] and Sr6 [Ge2 N6 ] with Ge-Ge Bonds.

Authors:  Lukas Link; Manisha Pathak; Franziska Jach; Primoz Koželj; Alim Ormeci; Peter Höhn; Rainer Niewa
Journal:  Angew Chem Int Ed Engl       Date:  2021-02-18       Impact factor: 15.336
  1 in total

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