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Literature DB >> 15673272

Iron-catalyzed oxidative homo-coupling of aryl Grignard reagents.

Abstract

[reaction: see text] Iron-catalyzed homo-coupling of aryl Grignard reagents was successfully developed. A variety of aryl Grignard reagents were efficiently converted into the corresponding symmetrical biaryls in the presence of 1-5 mol % FeCl3 and a stoichiometric amount of 1,2-dichloroethane.

Entities: Chemical

Year: 2005 PMID： 15673272 DOI： 10.1021/ol047509+

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

6 in total

1. Copper-Catalyzed Homo-Dimerization of Nitronates and Enolates under Oxygen Atmosphere.

Authors: Hien-Quang Do; Hung Tran-Vu; Olafs Daugulis
Journal: Organometallics Date: 2012-06-21 Impact factor: 3.876

2. Synthesis and applications of S-(trifluoromethyl)-2,8-bis(trifluoromethoxy)dibenzothiophenium triflate (Umemoto reagent IV).

Authors: Sagar R Mudshinge; Gerald B Hammond; Teruo Umemoto
Journal: J Fluor Chem Date: 2022-07-03 Impact factor: 2.226

Iron-catalyzed oxidative homo-coupling of aryl Grignard reagents.

1. Copper-Catalyzed Homo-Dimerization of Nitronates and Enolates under Oxygen Atmosphere.

2. Synthesis and applications of S-(trifluoromethyl)-2,8-bis(trifluoromethoxy)dibenzothiophenium triflate (Umemoto reagent IV).

3. Homocoupling of aryl halides in flow: Space integration of lithiation and FeCl(3) promoted homocoupling.

4. Copper-catalyzed oxidative homo- and cross-coupling of Grignard reagents using diaziridinone.

5. Exploration of Mechanochemical Activation in Solid-State Fluoro-Grignard Reactions.

6. Understanding the differences between iron and palladium in cross-coupling reactions.