Literature DB >> 15673271

New thermal source of dimethoxycarbene leading to zwitterionic intermediates and 2:1 stoichiometry in reaction with electrophilic alkenes.

Hongwei Zhou1, Grzegorz Mloston, John Warkentin.   

Abstract

[reaction: see text] At 50 degrees C, dimethyl dicyanofumarate and maleate react with 2 equiv of dimethoxycarbene to generate the products shown.

Entities:  

Year:  2005        PMID： 15673271     DOI： 10.1021/ol040068+

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  1 in total

Review 1.  Dialkyl dicyanofumarates and dicyanomaleates as versatile building blocks for synthetic organic chemistry and mechanistic studies.

Authors:  Grzegorz Mlostoń; Heinz Heimgartner
Journal:  Beilstein J Org Chem       Date:  2017-10-24       Impact factor: 2.883
  1 in total

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