Literature DB >> 15672155

Highly selective chromium-based ethylene trimerisation catalysts with bulky diphosphinoamine ligands.

Kevin Blann1, Annette Bollmann, John T Dixon, Fiona M Hess, Esna Killian, Hulisani Maumela, David H Morgan, Arno Neveling, Stephanus Otto, Matthew J Overett.   

Abstract

In situ prepared chromium catalysts containing bulky diphosphinoamine (PNP) ligands, upon activation with MAO, are extremely efficient catalysts for the trimerisation of ethylene to 1-hexene.

Entities:  

Year:  2004        PMID: 15672155     DOI: 10.1039/b412431f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Chain- and Regioselective Ethylene and Styrene Dimerization Reactions Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: New Insights on the Styrene Dimerization Mechanism.

Authors:  Do W Lee; Chae S Yi
Journal:  Organometallics       Date:  2010-01-01       Impact factor: 3.876

2.  Mechanistic Studies of Ethylene and α-Olefin Co-oligomerization Catalyzed by Chromium-PNP Complexes.

Authors:  Loi H Do; Jay A Labinger; John E Bercaw
Journal:  Organometallics       Date:  2012-07-23       Impact factor: 3.876

3.  NMR chemical shift analysis decodes olefin oligo- and polymerization activity of d0 group 4 metal complexes.

Authors:  Christopher P Gordon; Satoru Shirase; Keishi Yamamoto; Richard A Andersen; Odile Eisenstein; Christophe Copéret
Journal:  Proc Natl Acad Sci U S A       Date:  2018-06-11       Impact factor: 11.205

  3 in total

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