Literature DB >> 15649783

Chemical behavior of tungstate solutions. Part 1. A spectroscopic survey of the species involved.

Thierry Barré1, Laurent Arurault, François X Sauvage.   

Abstract

This study is focused on the composition and the evolution of tungstate ions solutions as a function of pH and increasing concentrations. The Raman analysis showed that, during the titration of the tungstate solutions, WO4(2-), HWO4- ions and probably W2O7(2-) , HW2O7(2-) and H2W2O7 solvated species could exist in aqueous solutions. For diluted solutions, additions of a strong acid does not cause any precipitation, whereas the formation of the unstable solid tungstic acid (H2WO4 or WO3.H2O) could occur in concentrated solutions.

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Year:  2005        PMID: 15649783     DOI: 10.1016/j.saa.2004.05.005

Source DB:  PubMed          Journal:  Spectrochim Acta A Mol Biomol Spectrosc        ISSN: 1386-1425            Impact factor:   4.098


  2 in total

1.  Direct C-C Bond Formation from Alkanes Using Ni-Photoredox Catalysis.

Authors:  Laura K G Ackerman; Jesus I Martinez Alvarado; Abigail G Doyle
Journal:  J Am Chem Soc       Date:  2018-10-16       Impact factor: 15.419

2.  Self-Limiting Adsorption of WO3 Oligomers on Oxide Substrates in Solution.

Authors:  Matthias Müllner; Jan Balajka; Michael Schmid; Ulrike Diebold; Stijn F L Mertens
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2017-08-16       Impact factor: 4.126

  2 in total

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