Literature DB >> 15649512

2,3-Epoxybrassinosteroids are intermediates in the biosynthesis of castasterone in seedlings of Secale cereale.

Andrey Antonchick1, Ales Svatos, Bernd Schneider, Olga V Konstantinova, Vladimir N Zhabinskii, Vladimir A Khripach.   

Abstract

The involvement of the 2,3-epoxybrassinosteroids secasterone and 2,3-diepisecasterone in the biosynthesis of castasterone has been demonstrated in seedlings of Secale cereale by LC-ESI-MS. Deuterated secasterone, upon administration to rye seedlings, was incorporated into castasterone and its 2beta- and 3beta-epimers. Administration of deuterated 2,3-diepisecasterone resulted in castasterone and 2-epicastasterone. A biosynthetic subpathway from typhasterol/teasterone via 2,3-epoxybrassinosteroid intermediates to castasterone is discussed.

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Year:  2005        PMID: 15649512     DOI: 10.1016/j.phytochem.2004.11.008

Source DB:  PubMed          Journal:  Phytochemistry        ISSN: 0031-9422            Impact factor:   4.072


  1 in total

1.  Occurrence of brassinosteroids and influence of 24-epibrassinolide with brassinazole on their content in the leaves and roots of Hordeum vulgare L. cv. Golden Promise.

Authors:  Andrzej Bajguz; Wacław Orczyk; Agnieszka Gołębiewska; Magdalena Chmur; Alicja Piotrowska-Niczyporuk
Journal:  Planta       Date:  2018-12-29       Impact factor: 4.116

  1 in total

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