| Literature DB >> 15631862 |
Cavit Uyanik1, Aslihan Malay, Azra S Ayna, James R Hanson, Peter B Hitchcock.
Abstract
The stereochemistry of the addition of methylmagnesium bromide to a steroidal 4,5-epoxy-3-ketone has been shown to be determined by the stereochemistry of the epoxide. The epoxidation to the corresponding 3-alkyl-3-hydroxy-4-enes by per-acid was determined by the stereochemistry of the allylic alcohol.Entities:
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Year: 2004 PMID： 15631862 DOI： 10.1016/j.steroids.2004.09.002
Source DB: PubMed Journal: Steroids ISSN： 0039-128X Impact factor: 2.668