Literature DB >> 15631444

Multipolymer solution-phase reactions: application to the Mitsunobu reaction.

Andrew M Harned1, Helen Song He, Patrick H Toy, Daniel L Flynn, Paul R Hanson.   

Abstract

The realization of the first polymer-on-polymer Mitsunobu reaction, in which a polymeric phosphine is used simultaneously with a polymeric azodicarboxylate, is reported. This strategy employs the use of soluble oligomers generated from ring-opening methathesis polymerization. 31P NMR analysis revealed that the two polymers were interacting to generate the Mitsunobu products. Application to several substrates, as well as comparison experiments with other polymeric reagents, is described.

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Year:  2005        PMID: 15631444     DOI: 10.1021/ja045188r

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  9 in total

1.  Immobilization on a Nanomagnetic Co/C Surface Using ROM Polymerization: Generation of a Hybrid Material as Support for a Recyclable Palladium Catalyst.

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Journal:  Adv Funct Mater       Date:  2010-12-21       Impact factor: 18.808

2.  Synthesis of N²-modified 7-methylguanosine 5'-monophosphates as nematode translation inhibitors.

Authors:  Karolina Piecyk; Richard E Davis; Marzena Jankowska-Anyszka
Journal:  Bioorg Med Chem       Date:  2012-06-10       Impact factor: 3.641

3.  Silica-Supported Oligomeric Benzyl Phosphate (Si-OBP) and Triazole Phosphate (Si-OTP) Alkylating Reagents.

Authors:  Pradip K Maity; Saqib Faisal; Alan Rolfe; Diana Stoianova; Paul R Hanson
Journal:  J Org Chem       Date:  2015-10-02       Impact factor: 4.354

4.  Monomer-on-monomer (MoM) Mitsunobu reaction: facile purification utilizing surface-initiated sequestration.

Authors:  Pradip K Maity; Alan Rolfe; Thiwanka B Samarakoon; Saqib Faisal; Ryan D Kurtz; Toby R Long; Alexander Schätz; Daniel L Flynn; Robert N Grass; Wendelin J Stark; Oliver Reiser; Paul R Hanson
Journal:  Org Lett       Date:  2010-12-01       Impact factor: 6.005

5.  High-load, hybrid Si-ROMP reagents.

Authors:  Alan Rolfe; Joanna K Loh; Pradip K Maity; Paul R Hanson
Journal:  Org Lett       Date:  2010-12-01       Impact factor: 6.005

6.  Intramolecular monomer-on-monomer (MoM) Mitsunobu cyclization for the synthesis of benzofused thiadiazepine-dioxides.

Authors:  Pradip K Maity; Quirin M Kainz; Saqib Faisal; Alan Rolfe; Thiwanka B Samarakoon; Fatima Z Basha; Oliver Reiser; Paul R Hanson
Journal:  Chem Commun (Camb)       Date:  2011-10-26       Impact factor: 6.222

7.  Improved method for the diimide reduction of multiple bonds on solid-supported substrates.

Authors:  Keith R Buszek; Neil Brown
Journal:  J Org Chem       Date:  2007-03-17       Impact factor: 4.354

8.  Synthesis of N,N-Diethylbenzamides via a Non-Classical Mitsunobu Reaction.

Authors:  J Mason Hoffman; Justin N Miller; Margaret E Gardner; Danielle R LePar; Rongson Pongdee
Journal:  Synth Commun       Date:  2014-01-01       Impact factor: 2.007

9.  Rasta resin-triphenylphosphine oxides and their use as recyclable heterogeneous reagent precursors in halogenation reactions.

Authors:  Xuanshu Xia; Patrick H Toy
Journal:  Beilstein J Org Chem       Date:  2014-06-20       Impact factor: 2.883

  9 in total

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