| Literature DB >> 15631444 |
Andrew M Harned1, Helen Song He, Patrick H Toy, Daniel L Flynn, Paul R Hanson.
Abstract
The realization of the first polymer-on-polymer Mitsunobu reaction, in which a polymeric phosphine is used simultaneously with a polymeric azodicarboxylate, is reported. This strategy employs the use of soluble oligomers generated from ring-opening methathesis polymerization. 31P NMR analysis revealed that the two polymers were interacting to generate the Mitsunobu products. Application to several substrates, as well as comparison experiments with other polymeric reagents, is described.Entities:
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Year: 2005 PMID: 15631444 DOI: 10.1021/ja045188r
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419