| Literature DB >> 15625002 |
Jun Lu1, Shun-Jun Ji, Yong-Chua Teo, Teck-Peng Loh.
Abstract
A chiral indium(III)-PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, alpha,beta-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee).Entities:
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Year: 2005 PMID： 15625002 DOI： 10.1021/ol047711c
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005