Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Triethylsilane-indium(III) chloride system as a radical reagent.

Literature DB >> 15606115

Triethylsilane-indium(III) chloride system as a radical reagent.

Naoki Hayashi¹, Ikuya Shibata, Akio Baba.

Abstract

[reaction: see text] A novel generation method of indium hydride (Cl2InH) was found by the transmetalation of InCl3 with Et3SiH. In the intramolecular cyclization of enynes, the previously reported system (NaBH4-InCl3) has a problem of side reactions with the coexistent borane. In contrast, the problem was solved by the presented system, which affords effective hydroindation of alkynes.

Entities: Chemical

Year: 2004 PMID： 15606115 DOI： 10.1021/ol047849v

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

Keyword Cloud
Cited

6 in total

1. Triarylphosphine Ligands with Hemilabile Alkoxy Groups. Ligands for Nickel(II)-Catalyzed Olefin Dimerization Reactions. Hydrovinylation of Vi-nylarenes, 1,3-Dienes, and Cycloisomerization of 1,6-Dienes.

Authors: Souvagya Biswas; Aibin Zhang; Balaram Raya; T V RajanBabu
Journal: Adv Synth Catal Date: 2014-07-01 Impact factor: 5.837

Triethylsilane-indium(III) chloride system as a radical reagent.

1. Triarylphosphine Ligands with Hemilabile Alkoxy Groups. Ligands for Nickel(II)-Catalyzed Olefin Dimerization Reactions. Hydrovinylation of Vi-nylarenes, 1,3-Dienes, and Cycloisomerization of 1,6-Dienes.

2. Reductions of aryl bromides in water at room temperature.

3. Tin-free enantioselective radical reactions using silanes.

4. EPR and pulsed ENDOR study of intermediates from reactions of aromatic azides with group 13 metal trichlorides.

5. 1,3,2-Diazaphospholene-Catalyzed Reductive Cyclizations of Organohalides.

Review 6. Main-Group Metal Complexes in Selective Bond Formations Through Radical Pathways.