Literature DB >> 15601032

Dielectric studies deny existence of ultraviscous fragile water.

Ayumi Minoguchi1, Ranko Richert, C Austen Angell.   

Abstract

The glass transition, a relaxation phenomenon, sets the low temperature limit to the liquid state. Glassy water that forms only under extreme quenching conditions is unstable against crystallization. Opinions differ on whether the glass transition can be observed at all. Here we measure the dielectric tan(delta for easily glassforming waterlike aqueous solutions, H2O-H2O2 and H2O-N2H4, to characterize the behavior of such systems during passage through their glass transitions. All show unambiguous Tg values of 136-140 K, the value generally assigned to pure water. However, the behavior of epsilon''/epsilon' is quite different from that in amorphous water in the same temperature range. Our findings eliminate "ultraviscous fragile liquid" as a possible description of water between 136 K and crystallization, but leave "ultraviscous strong liquid" a possibility to be considered.

Entities:  

Year:  2004        PMID: 15601032     DOI: 10.1103/PhysRevLett.93.215703

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  2 in total

1.  Water's second glass transition.

Authors:  Katrin Amann-Winkel; Catalin Gainaru; Philip H Handle; Markus Seidl; Helge Nelson; Roland Böhmer; Thomas Loerting
Journal:  Proc Natl Acad Sci U S A       Date:  2013-10-07       Impact factor: 11.205

2.  The glass transition in high-density amorphous ice.

Authors:  Thomas Loerting; Violeta Fuentes-Landete; Philip H Handle; Markus Seidl; Katrin Amann-Winkel; Catalin Gainaru; Roland Böhmer
Journal:  J Non Cryst Solids       Date:  2015-01-01       Impact factor: 3.531

  2 in total

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