| Literature DB >> 15600303 |
Sébastien Richeter1, Julius Rebek.
Abstract
A deep cavitand bearing a zinc (II) salen wall catalyzes the hydrolysis of para-nitrophenylcholine carbonate. The closed end of the cavitand properly positions the carbonyl function of the substrate for activation by the metal center. Substrate specificity for acetylcholine derivatives results from simultaneous cation-pi interactions and a C=O- - -Zn coordination bond.Entities:
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Year: 2004 PMID： 15600303 DOI： 10.1021/ja045167x
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419