Literature DB >> 15599442

Formation of racemic crystals of transition metal complexes by grinding 1 : 1 mixtures of enantiomeric crystals.

Asao Nakamura1, Tomohiro Sato, Reiko Kuroda.   

Abstract

Grinding a 1 : 1 enantiomeric mixture of chiral transition metal complex crystals and subsequent annealing afforded crystals of a racemic compound by diffusion and rearrangement of component molecules, without melting and without racemization of each enantiomeric species.

Entities:  

Year:  2004        PMID: 15599442     DOI: 10.1039/b409006c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Anticancer osmium complex inhibitors of the HIF-1α and p300 protein-protein interaction.

Authors:  Chao Yang; Wanhe Wang; Guo-Dong Li; Hai-Jing Zhong; Zhen-Zhen Dong; Chun-Yuen Wong; Daniel W J Kwong; Dik-Lung Ma; Chung-Hang Leung
Journal:  Sci Rep       Date:  2017-02-22       Impact factor: 4.379

  1 in total

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