Literature DB >> 15575785

Reactivity of phthalimide N-oxyl radical (PINO) toward the phenolic O-H bond. A kinetic study.

Enrico Baciocchi1, Maria Francesca Gerini, Osvaldo Lanzalunga.   

Abstract

The reactivity of the phthalimide N-oxyl radical (PINO) toward the OH bond of a series of substituted phenols was kinetically investigated in CH(3)CN. The reaction selectivity and the deuterium kinetic isotope effect were determined. Information on the kinetic solvent effect was also obtained with phenol as the substrate.

Entities:  

Year:  2004        PMID: 15575785     DOI: 10.1021/jo048656o

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  3 in total

Review 1.  Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions.

Authors:  Jordan E Nutting; Mohammad Rafiee; Shannon S Stahl
Journal:  Chem Rev       Date:  2018-04-30       Impact factor: 60.622

2.  An efficient and practical aerobic oxidation of benzylic methylenes by recyclable N-hydroxyimide.

Authors:  Jian Wang; Cheng Zhang; Xiao-Qing Ye; Wenting Du; Shenxin Zeng; Jian-Hong Xu; Hong Yin
Journal:  RSC Adv       Date:  2021-01-14       Impact factor: 3.361

3.  Biomimetic catalytic aerobic oxidation of C-sp(3)-H bonds under mild conditions using galactose oxidase model compound CuIIL.

Authors:  Xiao-Hui Liu; Hai-Yang Yu; Jia-Ying Huang; Ji-Hu Su; Can Xue; Xian-Tai Zhou; Yao-Rong He; Qian He; De-Jing Xu; Chao Xiong; Hong-Bing Ji
Journal:  Chem Sci       Date:  2022-07-28       Impact factor: 9.969

  3 in total

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