Literature DB >> 15568104

Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements via proton-induced reversible metal migration.

Christian Dubs1, Akiko Inagaki, Munetaka Akita.   

Abstract

Pairs of isomeric heterodinuclear complexes, [(cod)Ir(mu-PNNN)M(L)]BF4 and [(L)M(mu-PNNN)Ir(cod)]BF4, with switched metal arrangements are prepared in a specific manner by simply changing the addition order of the reagents.

Entities:  

Year:  2004        PMID: 15568104     DOI: 10.1039/b409514f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Metal-metal cooperative bond activation by heterobimetallic alkyl, aryl, and acetylide PtII/CuI complexes.

Authors:  Shubham Deolka; Orestes Rivada-Wheelaghan; Sandra L Aristizábal; Robert R Fayzullin; Shrinwantu Pal; Kyoko Nozaki; Eugene Khaskin; Julia R Khusnutdinova
Journal:  Chem Sci       Date:  2020-05-02       Impact factor: 9.825

  1 in total

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