Literature DB >> 15568098

Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism.

Joseph S M Samec1, Alida H Ell, Jan-E Bäckvall.   

Abstract

The negligible double kinetic deuterium isotope effect (k(HH)/k(DD)= 1.05) in the reaction where [2,3,4,5-Ph4(eta5-C4COH)Ru(CO)2H (2) transfers a hydride and a proton to N-phenyl-[1-(4-methoxyphenyl)ethylidene]amine (4) indicates that no bond to hydrogen is broken or formed in the rate-determining step.

Entities:  

Year:  2004        PMID： 15568098     DOI： 10.1039/b410698a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Hydrogenation of quinoline by ruthenium nanoparticles immobilized on poly(4-vinylpyridine).

Authors:  Roberto A Sánchez-Delgado; Nataliya Machalaba; Nkechia Ng-A-Qui
Journal:  Catal Commun       Date:  2007-12       Impact factor: 3.626

Review 2.  Efficient Aerobic Oxidation of Organic Molecules by Multistep Electron Transfer.

Authors:  Jie Liu; Arnar Guðmundsson; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2021-03-24       Impact factor: 16.823
  2 in total

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