| Literature DB >> 15568093 |
Shaheed A Mungur1, Stephen T Liddle, Claire Wilson, Mark J Sarsfield, Polly L Arnold.
Abstract
Lithium(I) and uranium(VI) amido-tethered Bu(t)-substituted N-heterocyclic carbene (NHC) complexes exhibit very distorted metal-carbene bonds; the corresponding magnesium(II) and mesityl-substituted NHC uranium(VI) complexes are undistorted; the distortion does not affect the ligand binding strength, suggesting a dominance of electrostatic character in closed-shell electropositive metal-carbene bonds.Entities:
Year: 2004 PMID： 15568093 DOI： 10.1039/b410074c
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222