Literature DB >> 15568082

[Ru(eta3-2-C3H4Me)(CO)(dppf)][SbF6]: a mononuclear 16e - ruthenium(II) catalyst for propargylic substitution and isomerization of HC[triple bond]CCPh2(OH).

Victorio Cadierno1, Josefina Díez, Sergio E García-Garrido, José Gimeno.   

Abstract

The 16e(-) derivative [Ru(eta3-2-C3H4Me)(CO)(dppf)][SbF6] catalyzes: (i) the propargylic substitution reaction of 1,1-diphenyl-2-propyn-1-ol with alcohols to produce propargylic ethers, and (ii) the formal isomerization of 1,1-diphenyl-2-propyn-1-ol into 3,3-diphenyl-2-propenal.

Entities:  

Year:  2004        PMID： 15568082     DOI： 10.1039/b410812d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Expeditious entry to novel 2-methylene-2,3-dihydrofuro[3,2-c] chromen-2-ones from 6-chloro-4-hydroxychromen-2-one and propargylic alcohols.

Authors:  Noel Nebra; Alba E Díaz-Álvarez; Josefina Díez; Victorio Cadierno
Journal:  Molecules       Date:  2011-08-02       Impact factor: 4.411

Review 2.  Electrophilic halogenations of propargyl alcohols: paths to α-haloenones, β-haloenones and mixed β,β-dihaloenones.

Authors:  Pakorn Bovonsombat; Punyanuch Sophanpanichkul; Satreerat Losuwanakul
Journal:  RSC Adv       Date:  2022-08-12       Impact factor: 4.036
  2 in total

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