Literature DB >> 15554645

A family of dioxo-molybdenum(VI) complexes of N2X heteroscorpionate ligands of relevance to molybdoenzymes.

Brian S Hammes1, Bal S Chohan, Justin T Hoffman, Simon Einwächter, Carl J Carrano.   

Abstract

Four new Mo(VI)-dioxo complexes of a family of N2X heteroscorpionate ligands are reported which, together with data already available for (TpR)-, provide a unique example of a comprehensive set of isostructural, isoelectronic complexes differing only in one biologically relevant donor atom. A study of these complexes allows for a direct comparison of structural, spectroscopic, and oxygen atom transfer reactivity properties of the Mo(VI)-dioxo center (of relevance to various families of molybdoenzymes) as a function of donor atom identity.

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Year:  2004        PMID： 15554645     DOI： 10.1021/ic049130p

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  5 in total

1.  Influence of the oxygen atom acceptor on the reaction coordinate and mechanism of oxygen atom transfer from the dioxo-Mo(VI) complex, Tp(iPr)MoO(2)(OPh), to tertiary phosphines.

Authors:  Partha Basu; Brian W Kail; Charles G Young
Journal:  Inorg Chem       Date:  2010-06-07       Impact factor: 5.165

2.  Dioxomolybdenum(VI) complexes with ene-1,2-dithiolate ligands: synthesis, spectroscopy, and oxygen atom transfer reactivity.

Authors:  Hideki Sugimoto; Susumu Tatemoto; Koichiro Suyama; Hiroyuki Miyake; Shinobu Itoh; Chao Dong; Jing Yang; Martin L Kirk
Journal:  Inorg Chem       Date:  2009-11-16       Impact factor: 5.165

3.  Quantitation of the ligand effect in oxo-transfer reactions of dioxo-Mo(VI) trispyrazolyl borate complexes.

Authors:  Partha Basu; Brian W Kail; Andrew K Adams; Victor N Nemykin
Journal:  Dalton Trans       Date:  2012-12-04       Impact factor: 4.390

4.  μ-Oxido-bis{[2,2-bis-(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κN,O,N]chloridooxidomolybdenum(V)} mono-hydrate.

Authors:  Amalija Golobič; Boris Ceh
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-11-24

5.  Syntheses and Biological Studies of Cu(II) Complexes Bearing Bis(pyrazol-1-yl)- and Bis(triazol-1-yl)-acetato Heteroscorpionate Ligands.

Authors:  Maura Pellei; Valentina Gandin; Luciano Marchiò; Cristina Marzano; Luca Bagnarelli; Carlo Santini
Journal:  Molecules       Date:  2019-05-07       Impact factor: 4.411
  5 in total

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