Literature DB >> 15548087

A very reliable method for determination of absolute configuration of chiral secondary alcohols by 1H NMR spectroscopy.

Yoshio Takeuchi1, Hidehito Fujisawa, Ryoji Noyori.   

Abstract

Surprisingly stable synperiplanar conformers of CFTA esters have led us to develop a new and very reliable method for assigning absolute configurations of even secondary alcohols having minimal structural differences, such as chiral benzhydrols and alpha-monodeuterated benzyl alcohols.

Entities:  

Year:  2004        PMID: 15548087     DOI: 10.1021/ol0479489

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Cyclohexanecarbonitriles: assigning configurations at quaternary centers from (13)C NMR CN chemical shifts.

Authors:  Fraser F Fleming; Guoqing Wei
Journal:  J Org Chem       Date:  2009-05-01       Impact factor: 4.354

2.  Chirality and numbering of substituted tropane alkaloids.

Authors:  Munir Humam; Tarik Shoul; Damien Jeannerat; Orlando Muñoz; Philippe Christen
Journal:  Molecules       Date:  2011-08-25       Impact factor: 4.411

  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.