Literature DB >> 15548044

Eta2-dba complexes of Pd(0): the substituent effect in Suzuki-Miyaura coupling.

Ian J S Fairlamb1, Anant R Kapdi, Adam F Lee.   

Abstract

The influence of aryl substituents in dibenzylidene acetone (dba) ligands, for Pd(0) complexes, has been evaluated for Suzuki-Miyaura cross-coupling reactions. Electron-withdrawing substituents such as NO(2) or CF(3) deactivate the catalyst species whereas strongly donating substituents such as OMe increase catalytic activity over that of unsubstituted dba ligands. [reaction: see text]

Entities:  

Year:  2004        PMID: 15548044     DOI: 10.1021/ol048413i

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  17 in total

1.  Construction of Tertiary Chiral Centers by Pd-catalyzed Asymmetric Allylic Alkylation of Prochiral Enolate Equivalents.

Authors:  Yusuke Kita; Yoshitaka Numajiri; Noriko Okamoto; Brian M Stoltz
Journal:  Tetrahedron       Date:  2015-09-16       Impact factor: 2.457

2.  Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters.

Authors:  Allen Y Hong; Nathan B Bennett; Michael R Krout; Thomas Jensen; Andrew M Harned; Brian M Stoltz
Journal:  Tetrahedron       Date:  2011-12-30       Impact factor: 2.457

3.  A FISCHER INDOLIZATION STRATEGY TOWARD THE TOTAL SYNTHESIS OF (-)-GONIOMITINE.

Authors:  Beau P Pritchett; Jun Kikuchi; Yoshitaka Numajiri; Brian M Stoltz
Journal:  Heterocycles       Date:  2017-02-15       Impact factor: 0.831

4.  Stereocontrolled total syntheses of isodomoic acids G and H via a unified strategy.

Authors:  Scott E Denmark; Jack Hung-Chang Liu; Joseck M Muhuhi
Journal:  J Org Chem       Date:  2010-12-01       Impact factor: 4.354

5.  Cross-coupling of aromatic bromides with allylic silanolate salts.

Authors:  Scott E Denmark; Nathan S Werner
Journal:  J Am Chem Soc       Date:  2008-12-03       Impact factor: 15.419

6.  Scope and mechanism of the Pt-catalyzed enantioselective diboration of monosubstituted alkenes.

Authors:  John R Coombs; Fredrik Haeffner; Laura T Kliman; James P Morken
Journal:  J Am Chem Soc       Date:  2013-07-18       Impact factor: 15.419

7.  A new class of easily activated palladium precatalysts for facile C-N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides.

Authors:  Mark R Biscoe; Brett P Fors; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2008-05-01       Impact factor: 15.419

8.  Asymmetric Ni-catalyzed conjugate allylation of activated enones.

Authors:  Joshua D Sieber; James P Morken
Journal:  J Am Chem Soc       Date:  2008-03-14       Impact factor: 15.419

9.  Organotrifluoroborates and monocoordinated palladium complexes as catalysts--a perfect combination for Suzuki-Miyaura coupling.

Authors:  Gary A Molander; Belgin Canturk
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

10.  Catalytic enantioselective total synthesis of (+)-eucomic acid.

Authors:  Benzi I Estipona; Beau P Pritchett; Robert A Craig; Brian M Stoltz
Journal:  Tetrahedron       Date:  2016-03-02       Impact factor: 2.457

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