Literature DB >> 15548034

Unexpected cross-coupling reaction between o-chloroaryl ketones and organomanganese reagents.

Gérard Cahiez1, Denis Luart, Fabien Lecomte.   

Abstract

Alkyl- and arylmanganese reagents react with o-chloro or o-bromoaryl ketones to give the substituted ketones in high yields. The cross-coupling reaction is performed under mild conditions (-60 to +40 degrees C, 30 min to 4 h) and takes place with excellent chemoselectivity. [reaction: see text]

Entities:  

Year:  2004        PMID: 15548034     DOI: 10.1021/ol048842g

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Radical pairs with rotational fluidity in the photochemical reaction of acetophenone and cyclohexane in the zeolite NAY: a (13)C CPMAS NMR and product analysis study.

Authors:  Ammee Amboya; Tina Nguyen; T Hien Huynh; Ashley Brown; Gretchen Ratliff; Heather Yonutas; Deniz Cizmeciyan; Arunkumar Natarajan; Miguel A Garcia Garibay
Journal:  Org Biomol Chem       Date:  2009-04-16       Impact factor: 3.876

Review 2.  Recent advance in heterocyclic organozinc and organomanganese compounds; direct synthetic routes and application in organic synthesis.

Authors:  Seung-Hoi Kim; Reuben D Rieke
Journal:  Molecules       Date:  2010-11-08       Impact factor: 4.411

  2 in total

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