Literature DB >> 15543307

New reactions in water: metal-free conversion of alcohols and ketones into alpha-iodoketones.

José Barluenga1, María Marco-Arias, Francisco González-Bobes, Alfredo Ballesteros, José M González.   

Abstract

Using water as the reaction medium, ketones can be transformed into alpha-iodoketones upon treatment with sodium iodide, hydrogen peroxide and an acid; interestingly, alpha-iodoketones can be also obtained from secondary alcohols through a metal-free tandem oxidation-iodination approach.

Entities:  

Year:  2004        PMID： 15543307     DOI： 10.1039/b411227j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Lewis acid catalysis and Green oxidations: sequential tandem oxidation processes induced by Mn-hyperaccumulating plants.

Authors:  Vincent Escande; Brice-Loïc Renard; Claude Grison
Journal:  Environ Sci Pollut Res Int       Date:  2014-09-30       Impact factor: 4.223

2.  I2-catalyzed intramolecular oxidative amination of C(sp3)-H bond: efficient access to 3-acylimidazo[1,2-a]pyridines under neat condition.

Authors:  Lilan Huang; Wenqing Yin; Jian Wang; Chunfang Gan; Yanmin Huang; Chusheng Huang; Yimiao He
Journal:  RSC Adv       Date:  2019-01-18       Impact factor: 4.036

3.  Iodine/water-mediated deprotective oxidation of allylic ethers to access α,β-unsaturated ketones and aldehydes.

Authors:  Yuntian Xue; Yaolong Yan; Kezhi Jiang; Weifeng Chen; Lei Yang
Journal:  RSC Adv       Date:  2020-04-14       Impact factor: 3.361
  3 in total

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