Literature DB >> 15543281

An N,P-disubstituted-2-aminophosphaalkene and lithium and potassium complexes of the deprotonated "phosphaamidinate" anion.

Rene T Boeré1, Marcus L Cole, Peter C Junk, Jason D Masuda, Gotthelf Wolmershäuser.   

Abstract

The reaction of DippPH2(Dipp = 2,6-iPr2C6H3) with DippN=C(p-CH3C6H4)Cl in refluxing xylenes affords DippP=C(p-CH3C6H4)N(H)Dipp; deprotonation with alkali metal reagents produces unique lithium and potassium complexes with the ligand in a different geometry to that of the free phosphaamidine.

Entities:  

Year:  2004        PMID： 15543281     DOI： 10.1039/b408994d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Butyl-bis[μ-4-(2,4,6-trimethyl-phenyl-amino)pent-3-en-2-onato][4-(2,4,6-trimethyl-phenyl-amino)pent-3-en-2-onato]dimagnesium.

Authors:  René T Boeré; Twyla Gietz
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-08-29

Review 2.  Stable cyclic carbenes and related species beyond diaminocarbenes.

Authors:  Mohand Melaimi; Michèle Soleilhavoup; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2010-11-15       Impact factor: 15.336

3.  Synthesis of phosphaformamidines and phosphaformamidinates.

Authors:  Maoying Song; Bruno Donnadieu; Michele Soleilhavoup; Guy Bertrand
Journal:  Chem Asian J       Date:  2007-07-02
  3 in total

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