Literature DB >> 15538850

Frame transformation relations for fluxional symmetric rotor dimers.

Horace T Crogman1, William G Harter.   

Abstract

The theory of frame transformation relation connecting body oriented angular momentum states and lab weakly coupled momentum states have been extended from rotor-electron to rotor-dimer systems. Coupling schemes are analyzed for weak and strong cases of correlation between lab and two different rotor body frames. It is shown that the frame transformation relation is a purely quantum effect at low angular momentum but an approach to a classical limit for high J. Symmetry analysis of frame transformation is compared to eigensolutions of model coupling Hamiltonian.

Year:  2004        PMID: 15538850     DOI: 10.1063/1.1786572

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  1 in total

1.  Spectral analysis of two coupled diatomic rotor molecules.

Authors:  Horace T Crogman; William G Harter
Journal:  Int J Mol Sci       Date:  2014-10-28       Impact factor: 5.923

  1 in total

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