Nuclear ordering in lithium and an upper limit on its ambient pressure superconducting transition temperature.

We have discovered spontaneous ordering of nuclear spins in lithium metal by NMR measurements at very low temperatures. In low magnetic fields, B<0.2 mT, the NMR spectra show a pronounced low-frequency anomaly. Also, nonadiabatic response to a slowly varying magnetic field was observed. A rich phase diagram with three different nonparamagnetic regions is proposed. We estimate a critical spin temperature T(c) approximately 350 nK at B=0. We also report the absence of superconductivity in lithium at normal pressure down to T(e) approximately 100 microK (B<10 nT).