Literature DB >> 15521751

Controlling photochemistry with distinct hydrophobic nanoenvironments.

Lakshmi S Kaanumalle1, Corinne L D Gibb, Bruce C Gibb, V Ramamurthy.   

Abstract

A combination of hydrophobic forces and guest templation drive the assembly of cavitands into molecular capsules. Encapsulated guests such as dibenzyl ketones reside in an essentially dry environment, and upon irradiation, undergo rearrangement processes that are templated by the shape of the 1 nm x 2 nm cavity.

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Year:  2004        PMID: 15521751     DOI: 10.1021/ja0450197

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  17 in total

1.  Kinetic resolution of constitutional isomers controlled by selective protection inside a supramolecular nanocapsule.

Authors:  Simin Liu; Haiying Gan; Andrew T Hermann; Steven W Rick; Bruce C Gibb
Journal:  Nat Chem       Date:  2010-08-08       Impact factor: 24.427

2.  Adaptations of guest and host in expanded self-assembled capsules.

Authors:  Dariush Ajami; Julius Rebek
Journal:  Proc Natl Acad Sci U S A       Date:  2007-10-02       Impact factor: 11.205

Review 3.  High-definition self-assemblies driven by the hydrophobic effect: synthesis and properties of a supramolecular nanocapsule.

Authors:  Simin Liu; Bruce C Gibb
Journal:  Chem Commun (Camb)       Date:  2008-06-06       Impact factor: 6.222

4.  Photophysics Applied to Cavitands and Capsules.

Authors:  Orion B Berryman; Henry Dube; Julius Rebek
Journal:  Isr J Chem       Date:  2011-07-01       Impact factor: 3.333

5.  Water-soluble cavitands promote hydrolyses of long-chain diesters.

Authors:  Qixun Shi; Matthew P Mower; Donna G Blackmond; Julius Rebek
Journal:  Proc Natl Acad Sci U S A       Date:  2016-08-01       Impact factor: 11.205

6.  Preparative scale and convenient synthesis of a water-soluble, deep cavitand.

Authors:  Simone Mosca; Yang Yu; Julius Rebek
Journal:  Nat Protoc       Date:  2016-07-07       Impact factor: 13.491

7.  Simulation optimization of spherical non-polar guest recognition by deep-cavity cavitands.

Authors:  Piyush P Wanjari; Bruce C Gibb; Henry S Ashbaugh
Journal:  J Chem Phys       Date:  2013-12-21       Impact factor: 3.488

8.  An improved synthesis of 'octa-acid' deep-cavity cavitand.

Authors:  Simin Liu; Sarah E Whisenhunt-Ioup; Corinne L D Gibb; Bruce C Gibb
Journal:  Supramol Chem       Date:  2011-01-01       Impact factor: 1.688

9.  Binding of cyclic carboxylates to octa-acid deep-cavity cavitand.

Authors:  Corinne L D Gibb; Bruce C Gibb
Journal:  J Comput Aided Mol Des       Date:  2013-11-12       Impact factor: 3.686

10.  Dendronized supramolecular nanocapsules: pH independent, water-soluble, deep-cavity cavitands assemble via the hydrophobic effect.

Authors:  Marco D Giles; Simin Liu; Roy L Emanuel; Bruce C Gibb; Scott M Grayson
Journal:  J Am Chem Soc       Date:  2008-10-11       Impact factor: 15.419

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