Literature DB >> 15514739

Applications of the parahydrogen phenomenon in inorganic chemistry.

Damir Blazina1, Simon B Duckett, John P Dunne, Cyril Godard.   

Abstract

The study of reaction mechanisms by NMR spectroscopy normally suffers from limitations in sensitivity that arise from the physical constraints of the detection method. An overview is presented of how chemical reactions can be studied using parahydrogen assisted NMR spectroscopy where detected signal strengths can exceed those normally seen by factors of over 28,000.

Year:  2004        PMID： 15514739     DOI： 10.1039/B409606A

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  7 in total

1.  High-resolution hyperpolarized in vivo metabolic 13C spectroscopy at low magnetic field (48.7mT) following murine tail-vein injection.

Authors:  Aaron M Coffey; Matthew A Feldman; Roman V Shchepin; Danila A Barskiy; Milton L Truong; Wellington Pham; Eduard Y Chekmenev
Journal:  J Magn Reson       Date:  2017-06-15       Impact factor: 2.229

2.  Real-Time High-Sensitivity Reaction Monitoring of Important Nitrogen-Cycle Synthons by 15N Hyperpolarized Nuclear Magnetic Resonance.

Authors:  Peter J Rayner; Marianna Fekete; Callum A Gater; Fadi Ahwal; Norman Turner; Aneurin J Kennerley; Simon B Duckett
Journal:  J Am Chem Soc       Date:  2022-05-04       Impact factor: 16.383

3.  Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between H2 and D2.

Authors:  Oliver P E Townrow; Simon B Duckett; Andrew S Weller; Jose M Goicoechea
Journal:  Chem Sci       Date:  2022-06-09       Impact factor: 9.969

4.  Probing signal amplification by reversible exchange using an NMR flow system.

Authors:  Ryan E Mewis; Kevin D Atkinson; Michael J Cowley; Simon B Duckett; Gary G R Green; Richard A Green; Louise A R Highton; David Kilgour; Lyrelle S Lloyd; Joost A B Lohman; David C Williamson
Journal:  Magn Reson Chem       Date:  2014-05-06       Impact factor: 2.447

5.  Demonstration of heterogeneous parahydrogen induced polarization using hyperpolarized agent migration from dissolved Rh(I) complex to gas phase.

Authors:  Kirill V Kovtunov; Danila A Barskiy; Roman V Shchepin; Aaron M Coffey; Kevin W Waddell; Igor V Koptyug; Eduard Y Chekmenev
Journal:  Anal Chem       Date:  2014-06-11       Impact factor: 6.986

6.  Production of Catalyst-Free Hyperpolarised Ethanol Aqueous Solution via Heterogeneous Hydrogenation with Parahydrogen.

Authors:  Oleg G Salnikov; Kirill V Kovtunov; Igor V Koptyug
Journal:  Sci Rep       Date:  2015-09-09       Impact factor: 4.379

7.  Investigating pyridazine and phthalazine exchange in a series of iridium complexes in order to define their role in the catalytic transfer of magnetisation from para-hydrogen.

Authors:  Kate M Appleby; Ryan E Mewis; Alexandra M Olaru; Gary G R Green; Ian J S Fairlamb; Simon B Duckett
Journal:  Chem Sci       Date:  2015-04-28       Impact factor: 9.825
  7 in total

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