| Literature DB >> 15493908 |
Eiji Shirakawa1, Ryotaro Morita, Teruhisa Tsuchimoto, Yusuke Kawakami.
Abstract
Molecular hydrogen adds to aliphatic and aromatic alkynylstannanes in the presence of a ruthenium catalyst, pushing the stannyl group to the adjacent carbon atom to give alpha-substituted vinylstannanes. This is the first achievement of hydrogenation of alkynylstannanes, which is applicable also to the deuteration affording precursors for an important class of deuterium-labeled compounds.Entities:
Year: 2004 PMID： 15493908 DOI： 10.1021/ja0458827
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419