| Literature DB >> 15479053 |
Michinori Suginome1, Lars Uehlin, Masahiro Murakami.
Abstract
Aminoboranes have been shown to be highly efficient and mild iminium ion generators in the Mannich-type aminative coupling of aldehydes with silyl ketene acetals. By using aminoboranes bearing bulky amino groups, such as a diisopropylamino group, free secondary amines can be successfully used as the amino component in a three-component Mannich reaction with aldehydes and silyl ketene acetals.Entities:
Year: 2004 PMID： 15479053 DOI： 10.1021/ja045827y
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419