| Literature DB >> 15476350 |
Anca Dumitrescu1, Valentyn L Rudzevich, Vadim D Romanenko, Alain Mari, Wolfgang W Schoeller, Didier Bourissou, Guy Bertrand.
Abstract
Persistent phosphinyl radicals featuring the 2,6-bis(trifluoromethyl)phenyl group were prepared and characterized. Their electronic structure was theoretically investigated, and their low-temperature dimerization into the corresponding diphosphines was found to be strongly inhibited when the sterically very demanding (tert-butyl)(trimethylsilyl)amino substituent was used.Entities:
Year: 2004 PMID： 15476350 DOI： 10.1021/ic049152b
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165