| Literature DB >> 15471500 |
Valeria Di Bussolo1, Micaela Caselli, Maria Rosaria Romano, Mauro Pineschi, Paolo Crotti.
Abstract
The reaction of alpha vinyl oxirane 5, prepared through a new route to the d-gulal system, with O-nucleophiles (alcohols and di-O-isopropylidene-alpha-d-monosaccharides) and C-nucleophiles (lithium alkyls) affords, in a completely stereoselective way, the corresponding 2-unsaturated alpha O- and C-glycosides having the same configuration as the starting epoxide.Entities:
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Year: 2004 PMID： 15471500 DOI： 10.1021/jo0491152
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354