Literature DB >> 15467859

Unexpected oxidative C-C cleavage in the metallation of 2-substituted imidazolium salts to give N-heterocyclic carbene complexes.

Anthony R Chianese1, Brian M Zeglis, Robert H Crabtree.   

Abstract

Imidazolium salts blocked at C2 with methyl or benzyl groups unexpectedly react with silver oxide to give N-heterocyclic carbene complexes of silver via an oxidative carbon-carbon bond cleavage.

Entities:  

Year:  2004        PMID： 15467859     DOI： 10.1039/b409672j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  N-Heterocyclic Olefins as Organocatalysts for Polymerization: Preparation of Well-Defined Poly(propylene oxide).

Authors:  Stefan Naumann; Anthony W Thomas; Andrew P Dove
Journal:  Angew Chem Int Ed Engl       Date:  2015-07-01       Impact factor: 15.336

2.  Stepwise Synthesis of Tetra-imidazolium Macrocycles and Their N-Heterocyclic Carbene Metal Complexes.

Authors:  Zili Li; Nuchareenat Wiratpruk; Peter J Barnard
Journal:  Front Chem       Date:  2019-04-24       Impact factor: 5.221
  2 in total

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