Literature DB >> 15455437

In the golden age of organocatalysis.

Peter I Dalko1, Lionel Moisan.   

Abstract

The term "organocatalysis" describes the acceleration of chemical reactions through the addition of a substoichiometric quantity of an organic compound. The interest in this field has increased spectacularly in the last few years as result of both the novelty of the concept and, more importantly, the fact that the efficiency and selectivity of many organocatalytic reactions meet the standards of established organic reactions. Organocatalytic reactions are becoming powerful tools in the construction of complex molecular skeletons. The diverse examples show that in recent years organocatalysis has developed within organic chemistry into its own subdiscipline, whose "Golden Age" has already dawned.

Year:  2004        PMID: 15455437     DOI: 10.1002/anie.200400650

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  87 in total

1.  Enantioselective construction of pyrrolidines by palladium-catalyzed asymmetric [3 + 2] cycloaddition of trimethylenemethane with imines.

Authors:  Barry M Trost; Steven M Silverman
Journal:  J Am Chem Soc       Date:  2012-03-02       Impact factor: 15.419

2.  Highly stereoselective formal [3 + 3] cycloaddition of enals and azomethine imines catalyzed by N-heterocyclic carbenes.

Authors:  Audrey Chan; Karl A Scheidt
Journal:  J Am Chem Soc       Date:  2007-04-04       Impact factor: 15.419

3.  A peptide-embedded trifluoromethyl ketone catalyst for enantioselective epoxidation.

Authors:  David K Romney; Scott J Miller
Journal:  Org Lett       Date:  2012-02-08       Impact factor: 6.005

4.  Hydrogen bond catalyzed enantioselective vinylogous Mukaiyama aldol reaction.

Authors:  Vijaya Bhasker Gondi; Michel Gravel; Viresh H Rawal
Journal:  Org Lett       Date:  2005-12-08       Impact factor: 6.005

5.  Organocatalysis in radical chemistry. Enantioselective alpha-oxyamination of aldehydes.

Authors:  Mukund P Sibi; Masayuki Hasegawa
Journal:  J Am Chem Soc       Date:  2007-03-16       Impact factor: 15.419

6.  A green chemistry approach to asymmetric catalysis: solvent-free and highly concentrated reactions.

Authors:  Patrick J Walsh; Hongmei Li; Cecilia Anaya de Parrodi
Journal:  Chem Rev       Date:  2007-05-27       Impact factor: 60.622

7.  Origins of stereoselectivity in Diels-Alder cycloadditions catalyzed by chiral imidazolidinones.

Authors:  Ruth Gordillo; K N Houk
Journal:  J Am Chem Soc       Date:  2006-03-22       Impact factor: 15.419

8.  A recyclable fluorous organocatalyst for Diels-Alder reactions.

Authors:  Qianli Chu; Wei Zhang; Dennis P Curran
Journal:  Tetrahedron Lett       Date:  2006-12-25       Impact factor: 2.415

9.  Origin of enantioselectivity in CF3-PIP-catalyzed kinetic resolution of secondary benzylic alcohols.

Authors:  Ximin Li; Peng Liu; K N Houk; Vladimir B Birman
Journal:  J Am Chem Soc       Date:  2008-09-26       Impact factor: 15.419

10.  One-pot diastreoselective synthesis of highly functionalized cyclohexenones: 2-oxo-N,4,6-triarylcyclohex-3-enecarboxamides.

Authors:  Mir Rasul Mousavi; Malek Taher Maghsoodlou; Sayyed Mostafa Habibi-Khorassani
Journal:  Mol Divers       Date:  2014-08-06       Impact factor: 2.943

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