| Literature DB >> 15387609 |
Josep Comelles1, Marcial Moreno-Mañas, Elisabet Pérez, Anna Roglans, Rosa M Sebastián, Adelina Vallribera.
Abstract
Cu(SbF6)2-AdamBox and copper(II) bis-(5-tert-butylsalicylaldehydate) catalyze the Michael addition in neutral media. Mechanistic studies, based on UV-vis, IR, and electrospray ionization mass spectrometry (ESI-MS), suggest that copper enolates of the beta-dicarbonyl formed in situ are the active nucleophilic species. Copyright 2004 American Chemical SocietyEntities:
Year: 2004 PMID： 15387609 DOI： 10.1021/jo049373z
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354