Wavelength dependence of first molecular hyperpolarizability of a dendrimer in solution.

The frequency dependence of the first molecular hyperpolarizability of a dendrimer incorporated with thiophene-stilbene based charge-transfer chromophores is investigated by using a nanosecond 1907 nm laser and a number of wavelengths ranging from 1160 to 1760 nm emitted from an optical parametric amplifier pumped by a 1 kHz 130 fs Ti:sapphire laser. The measured hyperpolarizabilities are compared with those calculated from the charge-transfer absorption spectrum involving a Kramers-Kronig transformation scheme. The Kramers-Kronig transformation analysis provides a satisfactory account of the dispersion of the first molecular hyperpolarizability over the entire excitation wavelength range measured. The Kramers-Kronig technique extends the Oudar-Chemla two-level model previously proposed for the first molecular hyperpolarizability and it can be used in the nonresonance as well as the resonance region where the Oudar-Chemla model fails. The Kramers-Kronig transformation scheme allows a consistent intrinsic hyperpolarizability beta(0) to be obtained from the measured beta(HRS) using different excitation wavelengths for the dendrimer. The comparison of beta(0) for the dendrimer, which contains three chromophores, with that of corresponding monomer chromophore suggests that the chromophores inside the dendrimer are independent. This gives the evidence of the site isolation effect of the dendrimer and substantiates the larger macroscopic optical nonlinearity recently obtained for the dendrimer.