| Literature DB >> 15355044 |
Effiette L O Sauer1, Louis Barriault.
Abstract
[reaction: see text] We report a novel and efficient diastereoselective synthesis of wiedemannic acid analogue 30 in 16 steps from 7 using a tandem oxy-Cope/Claisen/ene reaction as the key step. Comparison of NMR data between wiedemannic acid (1) and analogue 30 leads us to believe that the reported stereochemistry at the ring junction of 1 is incorrect.Entities:
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Year: 2004 PMID: 15355044 DOI: 10.1021/ol0487635
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005