Literature DB >> 15354225

Unique asymmetric catalysis of cis-beta metal complexes of salen and its related Schiff-base ligands.

Tsutomu Katsuki1.   

Abstract

Complexes of chiral salen and its related tetradentate Schiff-base ligands adopt three different configurations, trans, cis-alpha and cis-beta. Of these complexes, trans-complexes have been widely used as catalysts for various asymmetric reactions. However, recent studies have disclosed that cis-beta metallosalen and its related complexes show unique asymmetric catalyses that cannot be achieved by trans-metallosalen complexes. The present article summarizes generation of cis-beta metallosalen and its related complexes, their structural features, and their application to asymmetric syntheses.

Entities:  

Year:  2004        PMID： 15354225     DOI： 10.1039/b304133f

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN： 0306-0012            Impact factor:   54.564


  10 in total

1.  Asymmetric Synthesis of Gonytolide A: Strategic Use of an Aryl Halide Blocking Group for Oxidative Coupling.

Authors:  Xiaowei Wu; Takayuki Iwata; Adam Scharf; Tian Qin; Kyle D Reichl; John A Porco
Journal:  J Am Chem Soc       Date:  2018-04-25       Impact factor: 15.419

2.  Methods for direct alkene diamination, new & old.

Authors:  Sam de Jong; Daniel G Nosal; Duncan J Wardrop
Journal:  Tetrahedron       Date:  2012-03-21       Impact factor: 2.457

3.  Vanadium-catalyzed regioselective oxidative coupling of 2-hydroxycarbazoles.

Authors:  Lei Liu; Patrick J Carroll; Marisa C Kozlowski
Journal:  Org Lett       Date:  2015-01-15       Impact factor: 6.005

4.  Bis[(2-methyl-benz-yl)bis-(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis-(perchlorate).

Authors:  Ray J Butcher; Yilma Gultneh; T B Yisgedu
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-02-15

5.  Selective oxidative homo- and cross-coupling of phenols with aerobic catalysts.

Authors:  Young Eun Lee; Trung Cao; Carilyn Torruellas; Marisa C Kozlowski
Journal:  J Am Chem Soc       Date:  2014-05-05       Impact factor: 15.419

6.  Synthesis, Characterization, Anticancer, and Antioxidant Studies of Ru(III) Complexes of Monobasic Tridentate Schiff Bases.

Authors:  Ikechukwu P Ejidike; Peter A Ajibade
Journal:  Bioinorg Chem Appl       Date:  2016-08-11       Impact factor: 7.778

7.  Catalytic asymmetric 1,4-additions of beta-keto esters to nitroalkenes promoted by a bifunctional homobimetallic Co2-Schiff base complex.

Authors:  Makoto Furutachi; Zhihua Chen; Shigeki Matsunaga; Masakatsu Shibasaki
Journal:  Molecules       Date:  2010-01-22       Impact factor: 4.411

8.  Cooperative Al(salen)-pyridinium catalysts for the asymmetric synthesis of trans-configured β-lactones by [2+2]-cyclocondensation of acylbromides and aldehydes: investigation of pyridinium substituent effects.

Authors:  Patrick Meier; Florian Broghammer; Katja Latendorf; Guntram Rauhut; René Peters
Journal:  Molecules       Date:  2012-06-12       Impact factor: 4.411

9.  Monitoring Reaction Intermediates to Predict Enantioselectivity Using Mass Spectrometry.

Authors:  Roelant Hilgers; Sin Yong Teng; Anamarija Briš; Aleksandr Y Pereverzev; Paul White; Jeroen J Jansen; Jana Roithová
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-03       Impact factor: 16.823

10.  A Straightforward Electrochemical Approach to Imine- and Amine-bisphenolate Metal Complexes with Facile Control Over Metal Oxidation State.

Authors:  Michael R Chapman; Susan E Henkelis; Nikil Kapur; Bao N Nguyen; Charlotte E Willans
Journal:  ChemistryOpen       Date:  2016-04-15       Impact factor: 2.911
  10 in total

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