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Literature DB >> 15352184

Regio- and enantioselective iridium-catalyzed allylic alkylation with in situ activated P,C-chelate complexes.

Gunter Lipowsky¹, Nicole Miller, Günter Helmchen.

Abstract

Entities: Chemical

Year: 2004 PMID： 15352184 DOI： 10.1002/anie.200460016

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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8 in total

1. Mechanistically driven development of iridium catalysts for asymmetric allylic substitution.

Authors: John F Hartwig; Levi M Stanley
Journal: Acc Chem Res Date: 2010-09-28 Impact factor: 22.384

2. (R)-2,2'-BINAPHTHOYL-(S,S)-DI(1-PHENYLETHYL) AMINOPHOSPHINE. SCALABLE PROTOCOLS FOR THE SYNTHESES OF PHOSPHORAMIDITE (FERINGA) LIGANDS.

Authors: Craig R Smith; Daniel J Mans; T V Rajanbabu; Scott E Denmark; Son T Nguyen
Journal: Organic Synth Date: 2008

3. Enantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement.

Authors: Wen-Bo Liu; Noriko Okamoto; Eric J Alexy; Allen Y Hong; Kristy Tran; Brian M Stoltz
Journal: J Am Chem Soc Date: 2016-04-18 Impact factor: 15.419

4. Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysis.

Authors: Wen-Bo Liu; Corey M Reeves; Scott C Virgil; Brian M Stoltz
Journal: J Am Chem Soc Date: 2013-07-12 Impact factor: 15.419

Regio- and enantioselective iridium-catalyzed allylic alkylation with in situ activated P,C-chelate complexes.

1. Mechanistically driven development of iridium catalysts for asymmetric allylic substitution.

2. (R)-2,2'-BINAPHTHOYL-(S,S)-DI(1-PHENYLETHYL) AMINOPHOSPHINE. SCALABLE PROTOCOLS FOR THE SYNTHESES OF PHOSPHORAMIDITE (FERINGA) LIGANDS.

3. Enantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement.

4. Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysis.

5. Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates.

6. Tandem Rh-catalysis: decarboxylative β-keto acid and alkyne cross-coupling.

7. Z-Selective iridium-catalyzed cross-coupling of allylic carbonates and α-diazo esters.

8. Brønsted acid and Pd-PHOX dual-catalysed enantioselective addition of activated C-pronucleophiles to internal dienes.