| Literature DB >> 15345836 |
Chadwick D Sofield1, Marc D Walter, Richard A Andersen.
Abstract
The title compound, [Ti(C11H21Si2)2(NH2)], crystallizes as a bent metallocene, with the NH2 group oriented to maximize the pi interaction between the N atom and the Ti(III) center. The increased pi bonding is reflected in a short Ti-N bond length of 1.933 (3) A.Entities:
Year: 2004 PMID： 15345836 DOI： 10.1107/S0108270104018840
Source DB: PubMed Journal: Acta Crystallogr C ISSN： 0108-2701 Impact factor: 1.172