Literature DB >> 15345833

Aquabis(2-nitrobenzoato-kappaO)(1,10-phenanthroline-kappa2N,N')zinc(II).

Kou-Lin Zhang1, Jian-Guo Lin, Ya-Qiong Wang, Wen-Lin Xu, Jiu-Tong Chen.   

Abstract

The title compound, [Zn(C7H4NO4)2(C12H8N2)(H2O)], has been synthesized. X-Ray analysis reveals that it is a neutral zinc(II) mononuclear carboxylate complex based on mixed N- and O-donor ligands. The Zn atom is five-coordinate in a distorted trigonal-bipyramidal coordination environment involving two O atoms of two monodentate 2-nitrobenzoate molecules, two N atoms of a 1,10-phenanthroline molecule and one O atom of a water molecule. The axial positions are occupied by a carboxylate O atom from the 2-nitrobenzoate ligand and an N atom from the 1,10-phenanthroline ligand [N-Zn-O = 167.66 (9) degrees].

Entities:  

Year:  2004        PMID: 15345833     DOI: 10.1107/S0108270104018165

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Synthesis, crystallographic, spectroscopic studies and biological activity of new cobalt(II) complexes with bioactive mixed sulindac and nitrogen-donor ligands.

Authors:  Asia M Shalash; Hijazi I Abu Ali
Journal:  Chem Cent J       Date:  2017-05-10       Impact factor: 4.215

  1 in total

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