Literature DB >> 15340626

A new reaction: lead(IV) acetate-mediated oxidative fragmentation of homoallylic alcohols.

Marcelo D Preite1, Mauricio A Cuellar.   

Abstract

Treatment of a homoallylic alcohol with lead(IV) acetate in refluxing benzene for 2 hours results in an oxidative cleavage to give a carbonyl compound and an allylic acetate with high yield.

Entities:  

Year:  2004        PMID: 15340626     DOI: 10.1039/b405986g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Deconjugative α-Alkylation of Cyclohexenecarboxaldehydes: An Access to Diverse Terpenoids.

Authors:  Rachid Chahboun; José Manuel Botubol-Ares; María Jesús Durán-Peña; Fermín Jiménez; Ramón Alvarez-Manzaneda; Enrique Alvarez-Manzaneda
Journal:  J Org Chem       Date:  2021-06-15       Impact factor: 4.354

  1 in total

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