| Literature DB >> 15330613 |
Zhi-Hong Cheng1, Bo-Yang Yu, Geoffrey A Cordell, Sheng-Xiang Qiu.
Abstract
[reaction: see text] Quinovic acid glycosides were microbially deglycosylated by a Nocardia sp. to their aglycon quinovic acid and its biogenetic counterpart, cincholic acid (3), via an unprecedented carbon skeleton rearrangement involving a methyl group migration. The structures of the metabolites were established by ESI-LC/MS and 2D-NMR techniques.Entities:
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Year: 2004 PMID: 15330613 DOI: 10.1021/ol048787b
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005