Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Decamethyldizincocene, a stable compound of Zn(I) with a Zn-Zn bond.

Literature DB >> 15326350

Decamethyldizincocene, a stable compound of Zn(I) with a Zn-Zn bond.

Irene Resa¹, Ernesto Carmona, Enrique Gutierrez-Puebla, Angeles Monge.

Abstract

Unlike mercury, which has an extensive +1 oxidation state chemistry, zinc usually adopts the +2 oxidation state. Decamethyldizincocene, Zn2(eta5-C5Me5)2, an organometallic compound of Zn(I) formally derived from the dimetallic [Zn-Zn]2+ unit, has been isolated from the low-temperature (-10 degrees C) reaction of Zn(C5Me5)2 and Zn(C2H5)2 in diethyl ether. X-ray studies show that it contains two eclipsed Zn(eta5-C5Me5) fragments with a Zn-Zn distance (+/- standard deviation) of 2.305(+/-3) angstroms, indicative of a metal-metal bonding interaction.

Entities: Chemical

Year: 2004 PMID： 15326350 DOI： 10.1126/science.1101356

Source DB: PubMed Journal: Science ISSN： 0036-8075 Impact factor: 47.728

Keyword Cloud
Cited

14 in total

1. Theoretical studies on all-metal binuclear sandwich-like complexes M2(η 4-E 4) 2 (M=Al, Ga, In; E=Sb, Bi).

Authors: Congzhi Wang; Xiuhui Zhang; Jian Lu; Qianshu Li
Journal: J Mol Model Date: 2012-02-16 Impact factor: 1.810

2. Molecules containing rare-earth atoms solely bonded by transition metals.

Authors: Mikhail V Butovskii; Christian Döring; Viktor Bezugly; Frank R Wagner; Yuri Grin; Rhett Kempe
Journal: Nat Chem Date: 2010-06-27 Impact factor: 24.427

3. Identification of a uranium-rhodium triple bond in a heterometallic cluster.

Authors: Genfeng Feng; Mingxing Zhang; Penglong Wang; Shuao Wang; Laurent Maron; Congqing Zhu
Journal: Proc Natl Acad Sci U S A Date: 2019-08-19 Impact factor: 11.205

4. Formation of environmentally persistent free radicals (EPFRs) on ZnO at room temperature: Implications for the fundamental model of EPFR generation.

Authors: Matthew C Patterson; Mark F DiTusa; Cheri A McFerrin; R L Kurtz; Randall W Hall; E D Poliakoff; P T Sprunger
Journal: Chem Phys Lett Date: 2016-12-31 Impact factor: 2.328

5. Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene.

Authors: Zachary Call; Meagan Suchewski; Christopher A Bradley
Journal: J Vis Exp Date: 2017-03-20 Impact factor: 1.355

6. The tri-mu-hydrido-bis[(eta(5)-C (5)Me (5))aluminum(III)] theoretical study, the assets of sandwiched M(2)H (3) (M of 13th group elements) stability.

Authors: Abdeladim Guermoune; Al Mokhtar Lamsabhi; Driss Cherqaoui; Abdellah Jarid; Hafid Anane; Gabriel Merino
Journal: J Mol Model Date: 2009-08-12 Impact factor: 1.810

Decamethyldizincocene, a stable compound of Zn(I) with a Zn-Zn bond.

1. Theoretical studies on all-metal binuclear sandwich-like complexes M2(η 4-E 4) 2 (M=Al, Ga, In; E=Sb, Bi).

2. Molecules containing rare-earth atoms solely bonded by transition metals.

3. Identification of a uranium-rhodium triple bond in a heterometallic cluster.

4. Formation of environmentally persistent free radicals (EPFRs) on ZnO at room temperature: Implications for the fundamental model of EPFR generation.

5. Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene.

6. The tri-mu-hydrido-bis[(eta(5)-C (5)Me (5))aluminum(III)] theoretical study, the assets of sandwiched M(2)H (3) (M of 13th group elements) stability.

7. Carbenes as catalysts for transformations of organometallic iron complexes.

8. Energy decomposition analysis of single bonds within Kohn-Sham density functional theory.

9. Main-group elements as transition metals.

10. Bonding analysis of the donor-acceptor sandwiches CpE-MCp (E = B, Al, Ga; M = Li, Na, K; Cp = η⁵-C₅H₅).