Literature DB >> 15315437

An intramolecular Diels-Alder approach to the eunicelins: enantioselective total synthesis of ophirin B.

Michael T Crimmins1, Brandon H Brown.   

Abstract

The enantioselective synthesis of the eunicellin ophirin B has been completed. A ring-closing metathesis provides efficient access to the oxonene ring, and a highly diastereoselective intramolecular Diels-Alder reaction results in the formation of the hydrobenzofuran portion of the molecule.

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Year:  2004        PMID： 15315437     DOI： 10.1021/ja046574b

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  13 in total

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Journal:  J Am Chem Soc       Date:  2009-05-06       Impact factor: 15.419
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