| Literature DB >> 15315427 |
Bernhard Breit1, Daniel Breuninger.
Abstract
Desymmetrizing hydroformylation of bisalkenyl- and bisallylcarbinols could be achieved employing a chiral substrate-bound catalyst-directing group (o-DPPF) with excellent levels of diastereotopic alkene face and diastereotopic alkene group discrimination to give bifunctionalized chiral aldehydes in enantiomerically pure form.Entities:
Year: 2004 PMID: 15315427 DOI: 10.1021/ja0467364
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419